I´m quite new to this and might have not read every post on this topic yet, so forgive me if this has been discussed already five years ago.
Is it known what exactly the black surface coating of the gen dials is?
Paint, that is black pigment in some kind of binding agent.
Powder coating, this would be molten synthetic pigments without a binding agent.
Metal or oxidized metal.
It is not vitreous enamel for sure.
„Galvanically applied black paint“ is often mentioned when describing the original Rolex process. In a galvanic process, you can transfer metal, in form of ions, through an electrolyte, from one electrode to another electrode. Basics of chemistry. I wonder how it should be possible to apply „paint“ with a galvanic process.
Has anybody thought about the process used to make printed circuit boards?
I could imagine two methods, in both cases use a gold plated dial as a substrate, gold would be resistant against chemical attacks we try in the process.
- Apply the photosensitive coating / photoresist , expose and develop, so that the „gilt printing“ keeps covered by the photoresist. The rest of the dial is naked gold again at this point and can be plated with zinc, nickel, black chrome, whatever. After that, the photoresist masking is washed off with acetone.
- Apply black zinc... plating on the gold substrate. Photo process, this time negative, leave the „printing“ exposed and the rest of the surface covered. Use an acid that will dissolve the uncovered, black metal layer, but not the gold substrate below. wash off the photoresist.