The lume that last the longest is called W4, followed by C3 and W2. C1 and W9 are far behind. All these pigments come from a company called Tritec, the problem is that they only sell to watchmakers or registered companies from the watch industry.
But hopefully there are alternatives, the first one of course being W@tchlume, which is a trusted dealer here, but we can also think of Glonation (glonation.com - NOT A TD).
About applying a layer of varnish over the lume, please note that humidity will damage lume pigments, leading the lume to glow weaker, so if you want to apply lume on the outside of the watch (on a bezel for example), it's indeed necessary.