Most relumers just put the new layer over the existing rep lume. It makes the job much easier and safer.
If you really are after the best lume you can manage and want to start from scratch with a good base layer of ultra white, careful shaving with a scalpel is the only really practical way to remove the old lume for most dials (applied markers create their own problems).
Any solvent that will remove the old lume will almost certainly also soften and remove the dial printing and surface finish.
Extra precautions are needed doing this on older Tritium dials, as breathing in tritium dust is extremely hazardous to the health.
CARE IS NEEDED! Until you are well practised at working at that fine a level of precision, it is incredibly easy to mark a dial surface, particularly on rep dials. You must keep removing the old lume debris constantly to prevent it from marking the dial surface. I use an aerosol airduster.
A trick that can save lots of heartache is to protect the bulk of the dial surface with art masking fluid (a kind of liquid latex), I still use this at times on an irreplaceable dial as a kind of safety net.
Then if you do slip slightly, there is a good chance that the mask will save the dial from damage.
Rep dials with high gloss finish and applied markers like Rolex are the worst, the dial surface marks at the slightest touch and cleaning with Rodico more often than not will remove some of the applied markers and that can easily put a lovely scratch on your dial.
Pearls under glass, like the ones on a lot of Breitlings, are a separate small piece and after removing the bezel or bezel tab, can be lifted out and the old lume is fairly easy to clean out from underneath before reluming.
HOWEVER - many lume compounds deteriorate on exposure to moisture, so you MUST use a pigment that is suited to exposure to water (some have every particle encapsulated in a waterproof coating, some are just naturally immune to moisture deterioration). You should also use a binder with better than average adhesion.
Good Luck :wink: